Preview

Bulletin of Federal State University of Education. Series: Physics and Mathematics

Advanced search

Viscoelasticity of polymer hydrogel within the framework of the structural model

https://doi.org/10.18384/2949-5067-2025-2-6-18

Abstract

Aim: to consider the viscoelastic characteristics of a polymer hydrogel, namely, a polyvinylpyrrolidone and carboxymethylcellulose hydrogel, which were obtained for two values of the deformation amplitude in a fresh sample and in a swelled hydrogel sample.
Methodology. An approximation of the experimental data of dynamic measurements by the equations of the structural rheological model was carried out at individual intervals of the cyclic frequency of shear oscillations.
Results. The possibility of using the equations of the structural model to describe the frequency dependences of dynamic moduli is shown. The value of the coefficients of the rheological equations depends on both the deformation amplitude and the initial state of the hydrogel. Research implications. It is shown that the equations of the structural rheological model are capable of approximating the experimental data of dynamic measurements obtained for hydrogel samples at different deformation amplitudes.

About the Authors

M. P. Vekovishchev
State University of Humanities and Social Studies
Russian Federation

Mikhail P. Vekovishchev – Cand. Sci. (Phys.-Math.), Assoc. Prof., Department of Physics and Chemistry

Kolomna, Moscow region



E. A. Kirsanov
State University of Humanities and Social Studies
Russian Federation

Evgeny A. Kirsanov – Cand. Sci. (Phys.-Math.), Assoc. Prof., Department of Physics and Chemistry

Kolomna, Moscow region



References

1. Frolov, Yu. G. (2004). Course of Colloid Chemistry. Surface Phenomena and Disperse Systems. Moscow: «Alliyance» publ. (in Russ.).

2. Antipova, K. G. (2024). Polymer and composite hydrogel materials for biomedicine with adjustable mechanical characteristics [dissertation]. Moscow (in Russ.).

3. Alam, K., Iqbal, M., Hasan, A. & Al-Maskari, N. (2020). Rheological characterization of biological hydrogels in aqueous state. In: Journal of Applied Biotechnology Reports, 7 (3), 172–176. DOI: 10.30491/JABR.2020.109994.

4. Molchanov, V. S., Glukhov, S. A. & Philippova, O. E. (2023). Rheological behavior of polysaccharide hydrogels of alginate reinforced by small amount of halloysite nanotubes for extrusion 3D printing. In: Herald of Moscow University. Series 16. Biology, 78 (3S), 63–68 (in Russ.).

5. Ruobing, Bai, Baohong, Chen, Jiawei, Yang & Zhigang, Suo (2019). Tearing a hydrogel of complex rheology. In: Journal of the Mechanics and Physics of Solids, 125, 749–761.

6. Saha, N., Vyroubal, R., Shah, R., Takeshi, K. & Saha, P. (2013). Effect of strain on viscoelastic behavior of fresh, swelled and mineralized PVP-CMC hydrogel. In: AIP Conference Proceedings, 1526 (1), 301–309. DOI: 10.1063/1.4802624.

7. Kirsanov, E. A. & Matveenko, V. N. (2022). Viscosity and elasticity of structured liquids. Moscow: Technosphera publ. (in Russ.).

8. Vekovishchev, M. P. & Kirsanov, E. A. (2023). Non-Newtonian flow of structured systems. XXXVII. Viscoelasticity of a clay/nylon-11 polymer composite. In: Liquid Crystals and their Application, 23 (4), 67–75 (in Russ.).


Supplementary files

Review

Views: 5


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 2949-5083 (Print)
ISSN 2949-5067 (Online)