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Bulletin of State University of Education. Series: Physics and Mathematics

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Viscoelasticity of carbon nanotubes in a polymer matrix

https://doi.org/10.18384/2949-5067-2024-1-6-19

Abstract

Aim. We consider the viscoelastic characteristics of melts of polymer composites with filler in the form of carbon nanotubes.

Methodology. The experimental data of dynamic measurements are approximated by the equations of a structural rheological model at separate intervals of the cyclic frequency of shear oscillations.

Results. The possibility of applying the equations of the structural model to describe rheological curves under conditions of linear viscoelasticity is shown. The relationship of the coefficients of rheological equations with the state of the composite material structure is established.

Research implications. Equations are proposed that are capable of approximating experimental data at separate frequency intervals of shear oscillations corresponding to a certain structural state of the polymer melt and polymer composite.

About the Authors

M. P. Vekovishchev
State University of Humanities and Social Studies
Russian Federation

Mikhail P. Vekovishchev– Cand. Sci. (Phys.-Math.), Assoc. Prof., Department of Physics and Chemistry 



E. A. Kirsanov
State University of Humanities and Social Studies
Russian Federation

Evgeny A. Kirsanov – Cand. Sci. (Phys.-Math.), Assoc. Prof., Department of Physics and Chemistry



References

1. Ma A., Chinesta F., Mackley M. Rheological modeling of carbon nanotube aggregate suspensions. In: Journal of Rheology, 2009, vol. 52, iss. 6, pp. 1311–1330. DOI: 10.1122/1.2982932.

2. Ma A. W. K., Yearsley K. M., Chinesta F., Mackley M. R. A review of the microstructure and rheology of carbon nanotube suspensions. In: Proceedings of the Institution of Mechanical Engineers, Part N: Journal of Nanoengineering and Nanosystems, 2009, vol. 222, iss. 3, pp. 71–94. DOI: 10.1243/17403499JNN153.

3. Lahlou S., Sehaqui R., Lahlou N. Thermal transfer of Nanofluids based on carbon nanotubes/glycerol and study of their rheological behavior. In: MATEC Web of Conferences, 2019, vol. 286: 14th Congress of Mechanics (CMM2019), article number: 08003. DOI: 10.1051/matecconf/201928608003.

4. Skripkiunas G., Karpova E., Bendoraitiene J., Barauskas I., Drochytka R. Degree of MWCNT suspension dispersity and its influence on rheology of cement pastes. In: Selected papers of the 13th International Conference “Modern building materials, structures and techniques” (MBMST 2019, 16–17 May 2019, Vilnius, Lithuania). Vilnus, Vilnus Gediminas Technical University, 2019, pp. 166–174. DOI: 10.3846/mbmst.2019.022.

5. Dresel A., Teipel U. Jet Dispersion of Multiwall Carbon Nanotubes and Correlation with Suspension Rheology. In: Chemical Engineering Technology, 2020, vol. 43, iss. 5 (Special Issue: Particle and Powder Technology: PARTEC 2019), pp. 869–878. DOI: 10.1002/ceat.201900534.

6. Corker A. Formulation and Rheology of Carbon-based Materials for Printing of Conductive Three-dimensional Structures: PhD Thesis. University of Liverpool, 2022. 193 p.

7. Shramm G. A Practical Approach to Rheology and Rheometry (Rus. ed.: Lavygin I. A., transl., Kulichikhin V. G., ed. Osnovy prakticheskoy reologii i reometrii. Moscow, KolosS Publ., 2003. 312 p).

8. Barnes H. A. A Handbook of Elementary Rheology. Institute of Non-Newtonian Fluid Mechanics. Aberystwyth, University of Wales, Cambrian Printers, 2000. 201 p.

9. Woo D. K., Kim B. C., Lee S. J. Preparation and rheological behavior of polystyrene/multiwalled carbon nanotube composites by latex technology. In: Korea-Australia Rheology Journal, 2009, vol. 21, no. 3, pp. 185–191.

10. Kirsanov Ye. A., Matveyenko V. N. Vyazkost' i uprugost' strukturirovannykh zhidkostey [Viscosity and elasticity of structured liquids]. Moscow, Tekhnosfera Publ., 2022. 284 p.


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ISSN 2949-5083 (Print)
ISSN 2949-5067 (Online)